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[( p ‐Tol 3 Sn) 2 MoO 4 ] – A Polymeric Triorganotin Molybdate with (10,3)a Network Structure
Author(s) -
Kondracka Małgorzata,
Merzweiler Kurt
Publication year - 2011
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201000381
Subject(s) - molybdate , tetrahedron , crystal structure , trigonal crystal system , crystallography , chemistry , stereochemistry , inorganic chemistry
Abstract ( p ‐Tol 3 Sn) 2 MoO 4 was prepared by the reaction of p ‐Tol 3 SnCl with (NBu 4 ) 2 [Mo 6 O 19 ] and (NBu 4 )OH. The title compound crystallises trigonal with a = 2769.2(2) and c = 3576.3(3) pm, space group R 3. The crystal structure consists of MoO 4 tetrahedra that are linked by p ‐Tol 3 SnO 2 bipyramides to give a 3D network structure and additionally every second MoO 4 tetrahedron shares a corner with a terminal p ‐Tol 3 SnO tetrahedron. ( p ‐Tol 3 Sn) 2 MoO 4 exhibits an uninodal (10,3)a network which is related to the structure of (NBu 4 )[(Ph 3 Sn) 3 MoO 4 ]·CH 3 CN.