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Synthesis, Structural, and Electrical Characterization of two Novel Coordination Polymers based on a [1,2,3]‐Triazole Carboxylic Acid Derivative Ligand
Author(s) -
Lin JinRui,
Yao JiYuan,
Wang WenXiang,
Zhao Hong
Publication year - 2011
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201000346
Subject(s) - carboxylic acid , ligand (biochemistry) , polymer , hydrothermal circulation , polar , derivative (finance) , characterization (materials science) , coordination polymer , chemistry , 1,2,4 triazole , polymer chemistry , materials science , organic chemistry , chemical engineering , nanotechnology , receptor , physics , biochemistry , astronomy , financial economics , engineering , economics
Two new one‐dimensional chain coordination polymers were synthesized by reaction of 5‐methyl‐1‐phenyl‐1 H ‐1,2,3‐triazole‐4‐carboxylic acid (Hmptca) and CuCl 2 , or NiCl 2 , respectively, under hydrothermal conditions. Both have non‐centrosymmetric polar packing arrangements (polar point group C s ), which result in dielectric properties.