Synthesis and Structure of a Rare Unsolvated Bis(amidinato) Lanthanide Chloride, (Piso) 2 CeCl (Piso = [ t BuC(NAr) 2 ] – , Ar = C 6 H 3  i Pr 2 –2,6) | Zendy

Dröse Peter | Zendy; Hrib Cristian G. | Zendy; Hilpert Liane | Zendy; Edelmann Frank T. | Zendy

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Synthesis and Structure of a Rare Unsolvated Bis(amidinato) Lanthanide Chloride, (Piso) 2 CeCl (Piso = [ t BuC(NAr) 2 ] – , Ar = C 6 H 3 i Pr 2 –2,6)

Author(s) -

Dröse Peter,

Hrib Cristian G.,

Hilpert Liane,

Edelmann Frank T.

Publication year - 2011

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201000338

Subject(s) - lanthanide , chloride , chemistry , cerium , ligand (biochemistry) , crystallography , x ray crystallography , stereochemistry , diffraction , inorganic chemistry , ion , organic chemistry , physics , receptor , biochemistry , optics

Use of the very bulky amidinate ligand [ t BuC(NAr) 2 ] – (= Piso, Ar = C 6 H 3 i Pr 2 –2,6) allowed the synthesis and structural characterization of the chloro‐functional complex (Piso) 2 CeCl ( 1 ). Complex 1 represents a rare example of an unsolvated bis(amidinato) lanthanide chloride. An X‐ray diffraction study confirmed the presence of a pentacoordinate cerium(III) complex.

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