Synthesis, Characterization, and Magnetic Properties of Novel Cobalt(II) and Copper(II) Complexes with 5‐(Isonicotinamido)isophthalate Ligand | Zendy

Deng XiuJun | Zendy; Gu Wen | Zendy; Wang Li | Zendy; Zeng LingFei | Zendy; Liu Xin | Zendy

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Synthesis, Characterization, and Magnetic Properties of Novel Cobalt(II) and Copper(II) Complexes with 5‐(Isonicotinamido)isophthalate Ligand

Author(s) -

Deng XiuJun,

Gu Wen,

Wang Li,

Zeng LingFei,

Liu Xin

Publication year - 2011

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201000326

Subject(s) - isophthalic acid , thermogravimetric analysis , cobalt , ligand (biochemistry) , copper , crystallography , hydrothermal circulation , hydrothermal synthesis , crystal structure , chemistry , materials science , characterization (materials science) , diffraction , stereochemistry , inorganic chemistry , nanotechnology , organic chemistry , physics , polyester , receptor , chemical engineering , biochemistry , optics , engineering , terephthalic acid

Two new complexes, {[Co(INAIP) · H 2 O] · 2H 2 O} n ( 1 ), and {[Cu(INAIP)] · H 2 O} n ( 2 ) [H 2 INAIP = 5‐(isonicotinamido)isophthalic acid] were synthesized under hydrothermal conditions, and characterized by single‐crystal X‐ray structure determination, thermogravimetric analysis, X‐ray powder diffraction, and magnetic studies. In complex 1 both Co II atoms and INAIP 2– ligands act as four‐connected node, whereas in 2 both Cu II atoms and INAIP 2– ligands act as three‐connected node.

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