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Synthesis and Characterization of a New Silaborazine Derivative
Author(s) -
Cakmak Hasan,
Jansen Martin
Publication year - 2011
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201000300
Subject(s) - derivative (finance) , monomer , crystallography , molecule , hydride , characterization (materials science) , ring (chemistry) , mass spectrometry , diffraction , chemistry , planar , bar (unit) , crystal structure , stereochemistry , materials science , physics , nanotechnology , organic chemistry , hydrogen , optics , computer science , computer graphics (images) , chromatography , meteorology , financial economics , economics , polymer
The synthesis and characterization of a new silaborazine derivative, namely 1,1,3,5‐tetrachloro‐2,6‐dimethyl‐4‐hydride‐1‐silaborazine (TDSB) are reported. The monomeric TDSB molecule is structurally characterized by NMR and FT‐IR spectroscopy and mass spectrometry, and additionally investigated by single crystal X‐ray diffraction ( P $\bar{1}$ (No. 2); a = 7.2534(6) Å, b = 9.0788(7) Å, c = 9.1361(7) Å, α = 66.839(2)°, β = 89.348(2)°, γ = 80.502(2)°; Z = 2; R 1 = 0.0425 [3443 observed reflections with I > 2σ( I )]). The structure of TDSB is composed of an essentially planar SiB 2 N 3 ring.