Synthesis and Characterization of a New Silaborazine Derivative | Zendy

Cakmak Hasan | Zendy; Jansen Martin | Zendy

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Synthesis and Characterization of a New Silaborazine Derivative

Author(s) -

Cakmak Hasan,

Jansen Martin

Publication year - 2011

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201000300

Subject(s) - derivative (finance) , monomer , crystallography , molecule , hydride , characterization (materials science) , ring (chemistry) , mass spectrometry , diffraction , chemistry , planar , bar (unit) , crystal structure , stereochemistry , materials science , physics , nanotechnology , organic chemistry , hydrogen , optics , computer science , computer graphics (images) , chromatography , meteorology , financial economics , economics , polymer

The synthesis and characterization of a new silaborazine derivative, namely 1,1,3,5‐tetrachloro‐2,6‐dimethyl‐4‐hydride‐1‐silaborazine (TDSB) are reported. The monomeric TDSB molecule is structurally characterized by NMR and FT‐IR spectroscopy and mass spectrometry, and additionally investigated by single crystal X‐ray diffraction ( P $\bar{1}$ (No. 2); a = 7.2534(6) Å, b = 9.0788(7) Å, c = 9.1361(7) Å, α = 66.839(2)°, β = 89.348(2)°, γ = 80.502(2)°; Z = 2; R 1 = 0.0425 [3443 observed reflections with I > 2σ( I )]). The structure of TDSB is composed of an essentially planar SiB 2 N 3 ring.

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