A New 3D Supramolecular Manganese(II) Complex Constructed from Benzimidazole‐5,6‐dicarboxylate and Oxalate: Synthesis, Structural, and Magnetic Properties | Zendy

Geng JinPeng | Zendy; Wang ZhaoXi | Zendy; Wu QiongFang | Zendy; Li MingXing | Zendy; Xiao HongPing | Zendy

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A New 3D Supramolecular Manganese(II) Complex Constructed from Benzimidazole‐5,6‐dicarboxylate and Oxalate: Synthesis, Structural, and Magnetic Properties

Author(s) -

Geng JinPeng,

Wang ZhaoXi,

Wu QiongFang,

Li MingXing,

Xiao HongPing

Publication year - 2011

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201000295

Subject(s) - manganese , benzimidazole , oxalate , hydrogen bond , supramolecular chemistry , crystallography , intermolecular force , intramolecular force , antiferromagnetism , chemistry , magnetic susceptibility , materials science , molecule , stereochemistry , crystal structure , inorganic chemistry , physics , organic chemistry , condensed matter physics

A new manganese(II) complex [Mn 3 (bidc) 2 (C 2 O 4 )(H 2 O) 10 ] n ( 1 ) (bidc = benzimidazole‐5,6‐dicarboxylate) was synthesized and characterized by X‐ray crystallography. X‐ray diffraction shows that complex 1 has a neutral, one‐dimensional (1D) brick wall chain structure. With the intramolecular and intermolecular hydrogen bonding interactions, the adjacent chains are joined into a 3D suparmolecular architecture. IR spectroscopy and variable temperature magnetic susceptibility measurements were made, which indicated weak antiferromagnetic coupling between the Mn II ions in complex 1 .

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