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Solvothermal Synthesis of New Luminescent Zinc(II) Coordination Polymers with One‐Dimensional Homochiral Structures
Author(s) -
Duan Yulai,
Lin Zhien,
Stips Tobias,
Dehnen Stefanie
Publication year - 2010
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201000251
Subject(s) - zinc , zigzag , luminescence , photoluminescence , solvothermal synthesis , ligand (biochemistry) , photoexcitation , crystallography , polymer , coordination polymer , chemistry , wurtzite crystal structure , phenanthroline , chain (unit) , materials science , crystal structure , stereochemistry , organic chemistry , excited state , mathematics , optoelectronics , receptor , physics , astronomy , nuclear physics , biochemistry , geometry
By using a dual‐ligand approach, two new homochiral zinc(II) coordination polymers, Zn 2 (phen) 2 (H 2 O) 2 (cam) 2 · ethanol ( 1 ) and Zn(bipy)(cam) ( 2 ) [phen = 1,10‐phenanthroline, bipy = 2,2′‐bipyridine, H 2 cam = (1 R ,3 S )‐(+)‐camphoric acid] have been synthesized under solvothermal conditions. Compound 1 has a zigzag chain‐like structure and compound 2 has a linear chain‐like structure. The two compounds exhibit intense photoluminescence upon photoexcitation at 280 and 290 nm, respectively.