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New Development in Rare Earth Metal Complexes Containing Anionic Bis(imino)pyrrolyl and Bis(phosphanyl)amide Ligands
Author(s) -
Li Tianshu,
Jenter Jelena,
Roesky Peter W.
Publication year - 2010
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201000169
Subject(s) - steric effects , amide , reactivity (psychology) , rare earth , ligand (biochemistry) , chemistry , coordination sphere , metal , coordination complex , catalysis , polymer chemistry , stereochemistry , organic chemistry , receptor , biochemistry , mineralogy , medicine , alternative medicine , pathology
Rare earth element complexes with the very bulky 2,5‐bis{ N ‐(2,6‐diisopropylphenyl)iminomethyl}pyrrolyl and the sterically less demanding bis(phosphanyl)amide ligand, (PPh 2 ) 2 N – in the coordination sphere are reviewed in this research report. The coordination chemistry, the reactivity, and the catalytic application of the corresponding complexes are discussed.