Metal Complexes of Dyes, XII [1], Halfsandwich Complexes of Ruthenium, Cobalt, Rhodium, Iridium with Iminocarboxylaten from 4‐(4′‐Nitrophenylazo)aniline (Disperse Orange 3) or 4,4′‐Diaminoazobenzene and 2‐Oxocarboxylates | Zendy

Kühlwein Frank | Zendy; Beck Wolfgang | Zendy

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Metal Complexes of Dyes, XII [1], Halfsandwich Complexes of Ruthenium, Cobalt, Rhodium, Iridium with Iminocarboxylaten from 4‐(4′‐Nitrophenylazo)aniline (Disperse Orange 3) or 4,4′‐Diaminoazobenzene and 2‐Oxocarboxylates

Author(s) -

Kühlwein Frank,

Beck Wolfgang

Publication year - 2010

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201000162

Subject(s) - iridium , chemistry , aniline , ruthenium , rhodium , metal , polymer chemistry , benzene , medicinal chemistry , organic chemistry , catalysis

The condensation of the amino groups of 4‐(4′‐nitrophenylazo)aniline or of 4,4′‐diaminoazo‐benzene with 2‐oxocarboxylates at chlorido bridged half‐sandwich complexes [(C 5 Me 5 ) M Cl 2 ] 2 ( M = Rh, Ir), [(p‐cymene)RuCl 2 ] 2 or of [(C 5 Me 5 )(Co(CO)I 2 ] provides a convenient way to attach azodyes to a metal ion via an 2‐iminocarboxylate ligand.

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