Synthesis, Crystal Structure, and Magnetic Properties of a New 2D Copper(II) Polymer Constructed by μ 1,5 ‐Dicyanamide and Sulfonate Anion Bridges | Zendy

Zhou QiJi | Zendy; Yao XueJun | Zendy; Hao LanFang | Zendy; Ouyang Yan | Zendy; Xu JingYuan | Zendy; Xie ChengZhi | Zendy; Lou JianShi | Zendy

Premium

Synthesis, Crystal Structure, and Magnetic Properties of a New 2D Copper(II) Polymer Constructed by μ 1,5 ‐Dicyanamide and Sulfonate Anion Bridges

Author(s) -

Zhou QiJi,

Yao XueJun,

Hao LanFang,

Ouyang Yan,

Xu JingYuan,

Xie ChengZhi,

Lou JianShi

Publication year - 2010

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201000106

Subject(s) - dicyanamide , sulfonate , copper , crystallography , crystal structure , ferromagnetism , ion , materials science , polymer , chemistry , inorganic chemistry , condensed matter physics , physics , organic chemistry , metallurgy , sodium , composite material , ionic liquid , catalysis

A new two‐dimensional (2D) polymer, [Cu(pmt)(dca)] n [pmt = 2‐(2‐pyridymethylamino)ethanesulfonate, dca = dicyanamide] ( 1 ), was synthesized and characterized by single‐crystal X‐ray diffraction, elemental analysis, IR spectroscopy, and magnetic measurements. X‐ray structure analysis revealed that the compound contains [Cu(μ 1,5 ‐dca)] n chains, which are further connected by bridging sulfonate anions of pmt ligands to result in (4,4)‐connected 2D sheets. The magnetic susceptibilities (2–300 K) of 1 were investigated, and indicated that the complex exhibits a weak ferromagnetic interaction between the copper(II) ions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research