Synthesis of Er 5 (BO 3 ) 2 F 9  and Properties of  RE  5 (BO 3 ) 2 F 9  ( RE  = Er, Yb) | Zendy

Haberer Almut | Zendy; Kaindl Reinhard | Zendy; Konzett Jürgen | Zendy; Glaum Robert | Zendy; Huppertz Hubert | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis of Er 5 (BO 3 ) 2 F 9 and Properties of RE 5 (BO 3 ) 2 F 9 ( RE = Er, Yb)

Author(s) -

Haberer Almut,

Kaindl Reinhard,

Konzett Jürgen,

Glaum Robert,

Huppertz Hubert

Publication year - 2010

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201000085

Subject(s) - raman spectroscopy , crystal structure , crystallography , x ray crystallography , materials science , diffraction , single crystal , chemistry , analytical chemistry (journal) , physics , optics , chromatography

Er 5 (BO 3 ) 2 F 9 was synthesised under conditions of 3 GPa and 800 °C in a Walker‐type multianvil apparatus. The crystal structure was determined on the basis of single‐crystal X‐ray diffraction data, collected at room temperature. Er 5 (BO 3 ) 2 F 9 is isotypic to the recently synthesised Yb 5 (BO 3 ) 2 F 9 and crystallises in C 2/ c with the lattice parameters a = 2031.2(4) pm, b = 609.5(2) pm, c = 824.6(2) pm, and β = 100.29(3)°. The physical properties of RE 5 (BO 3 ) 2 F 9 ( RE = Er, Yb) including high temperature behaviour and single crystal IR‐ / Raman spectroscopy were investigated.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research