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Polyether Adducts of d‐Block Metal Compounds as Starting Materials for New Cluster Compounds
Author(s) -
Crochet Aurélien,
Fromm Katharina M.
Publication year - 2010
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201000022
Subject(s) - diglyme , chemistry , dimethoxyethane , halide , adduct , metal , metal halides , ether , alkali metal , inorganic chemistry , medicinal chemistry , polymer chemistry , solvent , organic chemistry , electrolyte , electrode
New crystalline cobalt, nickel, zinc, and mercury halide adducts with polyethers as ligands have been isolated, characterized, and identified as [Co(μ‐Cl) 2 CoCl 2 (glyme) 2 ] (glyme = 1,2‐dimethoxyethane), cis ‐[CoI 2 (H 2 O) 2 (glyme) 2 ] 2+ [CoI 4 ] 2– , [NiI 2 (glyme) 2 ], [ZnI 2 (glyme)], [HgCl 2 (glyme)], [CoI 2 (diglyme)] (diglyme = bis(2‐methoxyethyl)ether), [ZnI 2 (diglyme)], [HgI 2 (diglyme)], [CoCl(μ‐Cl)(diglyme)] 2 , [NiI(μ‐I)(diglyme)] 2 , [Co(μ‐Cl)(triglyme)] 2 2+ [CoCl 2 (μ‐Cl)] 2 2– , and cis ‐[(NiI 2 )(triglyme)] n . These compounds were obtained from the metal halide salts in solution of glyme or diglyme, and some of them show unusual coordination numbers and arrangements.