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Two Related Porous Thioindates with T 3 Clusters, (H 2 DAH) 3 In 10 S 18 ·6H 2 O and (H 2 DAH) 3 In 10 S 18
Author(s) -
Zhang MingHui,
Zhu QinYu,
Bian GuoQing,
Lei ZhiXin,
Jiang JianBing,
Dai Jie
Publication year - 2010
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200900444
Subject(s) - diamine , solvent , microstructure , reagent , chemistry , porosity , crystal structure , crystallography , crystal (programming language) , reaction conditions , polymer chemistry , catalysis , organic chemistry , computer science , programming language
Two high porous thioindates with 1,6‐diaminohexane (DAH), DAH‐InS‐ 1 and DAH‐InS‐ 2 , were prepared by solvothermal reaction. Though the same T 3 supertetrahedral frameworks were reported, the cations are different. DAH is a non‐cyclic diamine and also an economical reagent for synthesis. Because of the structural difference of the structural directing agents, the dimensions of crystal cells of DAH‐InS‐ 1 and DAH‐InS‐ 2 are elongated and the total volumes for the cation and solvent are 74.6 and 72.1 % (Platon) larger relative to those reported previously. The two compounds were obtained in one reaction system by controlling the reaction time. Their structures are briefly discussed and the correlativity of crystal shape with the parameters of microstructure is discussed.