Hydrothermal Syntheses and Crystal Structures of Two New Three‐dimensional Coordination Polymers Based on 4‐Pyrid‐3‐ylbenzoic Acid | Zendy

Guo Feng | Zendy

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Hydrothermal Syntheses and Crystal Structures of Two New Three‐dimensional Coordination Polymers Based on 4‐Pyrid‐3‐ylbenzoic Acid

Author(s) -

Guo Feng

Publication year - 2010

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200900412

Subject(s) - coordination polymer , hydrothermal circulation , manganese , hydrothermal synthesis , elemental analysis , polymer , crystallography , infrared spectroscopy , crystal structure , cobalt , chemistry , hydrothermal reaction , topology (electrical circuits) , single crystal , net (polyhedron) , materials science , inorganic chemistry , chemical engineering , organic chemistry , mathematics , combinatorics , engineering , geometry

Two new coordination polymers [Co 2 (pbc) 4 (H 2 O)] n ( 1 ) and [Mn(pbc) 2 ] ( 2 ) (Hpbc = 4‐pyrid‐3‐ylbenzoic acid) were obtained by hydrothermal reaction and characterized by elemental analysis, IR spectroscopy, and single‐crystal X‐ray diffraction. Compound 1 features a 3D network with a four‐connected 6 6 net constructed from secondary building units of dinuclear cobalt. Compound 2 exhibits a six‐connected 4 12 · 6 3 topology based on dinuclear manganese.

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