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Hydrothermal Syntheses and Crystal Structures of Two New Three‐dimensional Coordination Polymers Based on 4‐Pyrid‐3‐ylbenzoic Acid
Author(s) -
Guo Feng
Publication year - 2010
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200900412
Subject(s) - coordination polymer , hydrothermal circulation , manganese , hydrothermal synthesis , elemental analysis , polymer , crystallography , infrared spectroscopy , crystal structure , cobalt , chemistry , hydrothermal reaction , topology (electrical circuits) , single crystal , net (polyhedron) , materials science , inorganic chemistry , chemical engineering , organic chemistry , mathematics , combinatorics , engineering , geometry
Two new coordination polymers [Co 2 (pbc) 4 (H 2 O)] n ( 1 ) and [Mn(pbc) 2 ] ( 2 ) (Hpbc = 4‐pyrid‐3‐ylbenzoic acid) were obtained by hydrothermal reaction and characterized by elemental analysis, IR spectroscopy, and single‐crystal X‐ray diffraction. Compound 1 features a 3D network with a four‐connected 6 6 net constructed from secondary building units of dinuclear cobalt. Compound 2 exhibits a six‐connected 4 12 · 6 3 topology based on dinuclear manganese.