Solvothermal Synthesis, Crystal Structure, and Properties of a New Organic‐Templated Holmium Sulfate with 1D Single Ladder Chains | Zendy

Zhou Wanli | Zendy; Ding Xiaorun | Zendy; Zhang Zhibin | Zendy; Zheng Lei | Zendy; Xu Yan | Zendy; Zhu Dunru | Zendy

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Solvothermal Synthesis, Crystal Structure, and Properties of a New Organic‐Templated Holmium Sulfate with 1D Single Ladder Chains

Author(s) -

Zhou Wanli,

Ding Xiaorun,

Zhang Zhibin,

Zheng Lei,

Xu Yan,

Zhu Dunru

Publication year - 2010

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200900397

Subject(s) - crystallography , thermogravimetric analysis , single crystal , holmium , diffraction , solvothermal synthesis , crystal structure , materials science , infrared spectroscopy , sulfate , chemistry , powder diffraction , laser , organic chemistry , optics , physics , metallurgy

A new organic amine templated 1D holmium sulfate (C 2 H 8 N)[Ho(SO 4 ) 2 · H 2 O] ( 1 ) has been synthesized and solvothermally and structurally characterized by single‐crystal X‐ray diffraction, IR spectroscopy, thermogravimetric and X‐ray diffraction analyses as well as scanning electron microscopy (SEM). The structure of framework 1 is constructed from HoO 8 polyhedra and SO 4 tetrahedra. S(1) and S(2) connects Ho(1) and its crystallographic partners by using three S–O–Ho linkages to generate double chains, whereas the adjacent double chain are connected by μ 3 ‐O (O 5 ) atoms to form a novel single ladder chains.

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