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Solvothermal Synthesis, Crystal Structure, and Properties of a New Organic‐Templated Holmium Sulfate with 1D Single Ladder Chains
Author(s) -
Zhou Wanli,
Ding Xiaorun,
Zhang Zhibin,
Zheng Lei,
Xu Yan,
Zhu Dunru
Publication year - 2010
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200900397
Subject(s) - crystallography , thermogravimetric analysis , single crystal , holmium , diffraction , solvothermal synthesis , crystal structure , materials science , infrared spectroscopy , sulfate , chemistry , powder diffraction , laser , organic chemistry , optics , physics , metallurgy
A new organic amine templated 1D holmium sulfate (C 2 H 8 N)[Ho(SO 4 ) 2 · H 2 O] ( 1 ) has been synthesized and solvothermally and structurally characterized by single‐crystal X‐ray diffraction, IR spectroscopy, thermogravimetric and X‐ray diffraction analyses as well as scanning electron microscopy (SEM). The structure of framework 1 is constructed from HoO 8 polyhedra and SO 4 tetrahedra. S(1) and S(2) connects Ho(1) and its crystallographic partners by using three S–O–Ho linkages to generate double chains, whereas the adjacent double chain are connected by μ 3 ‐O (O 5 ) atoms to form a novel single ladder chains.