A 3D Metal‐organic Framework Containing [Cd(3‐CPOA)]  n   (3‐CPOA 2–  = 3‐Carboxyphenoxyacetato Dianion) Expanded by 4,4′‐Bipyridine | Zendy

Deng ZhaoPeng | Zendy; Huo LiHua | Zendy; Gao Shan | Zendy; Zhao Hui | Zendy

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A 3D Metal‐organic Framework Containing [Cd(3‐CPOA)] n (3‐CPOA 2– = 3‐Carboxyphenoxyacetato Dianion) Expanded by 4,4′‐Bipyridine

Author(s) -

Deng ZhaoPeng,

Huo LiHua,

Gao Shan,

Zhao Hui

Publication year - 2010

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200900374

Subject(s) - thermogravimetric analysis , hydrothermal circulation , metal organic framework , infrared spectroscopy , crystallography , elemental analysis , metal , bipyridine , hydrothermal reaction , hydrothermal synthesis , chemistry , spectroscopy , single crystal , materials science , crystal structure , inorganic chemistry , nuclear chemistry , organic chemistry , chemical engineering , physics , adsorption , engineering , quantum mechanics

The hydrothermal reaction of Cd(NO 3 ) · 4H 2 O with 4,4′‐bipyridine (bipy) and 3‐carboxyphenoxyacetatic acid (3‐H 2 CPOA) afforded a 3D metal‐organic framework (MOF) [Cd(3‐CPOA)(bipy)] n · 3.5 n H 2 O, which was characterized by elemental analyses, IR spectroscopy, thermogravimetric analyses, and X‐ray diffraction. The single‐crystal structural analysis revealed that it has a Cds‐type topological network with 1D channels that contain encapsulated water molecular tapes.

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