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A 3D Metal‐organic Framework Containing [Cd(3‐CPOA)] n (3‐CPOA 2– = 3‐Carboxyphenoxyacetato Dianion) Expanded by 4,4′‐Bipyridine
Author(s) -
Deng ZhaoPeng,
Huo LiHua,
Gao Shan,
Zhao Hui
Publication year - 2010
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200900374
Subject(s) - thermogravimetric analysis , hydrothermal circulation , metal organic framework , infrared spectroscopy , crystallography , elemental analysis , metal , bipyridine , hydrothermal reaction , hydrothermal synthesis , chemistry , spectroscopy , single crystal , materials science , crystal structure , inorganic chemistry , nuclear chemistry , organic chemistry , chemical engineering , physics , adsorption , engineering , quantum mechanics
Abstract The hydrothermal reaction of Cd(NO 3 ) · 4H 2 O with 4,4′‐bipyridine (bipy) and 3‐carboxyphenoxyacetatic acid (3‐H 2 CPOA) afforded a 3D metal‐organic framework (MOF) [Cd(3‐CPOA)(bipy)] n · 3.5 n H 2 O, which was characterized by elemental analyses, IR spectroscopy, thermogravimetric analyses, and X‐ray diffraction. The single‐crystal structural analysis revealed that it has a Cds‐type topological network with 1D channels that contain encapsulated water molecular tapes.