A Cyclic Hydroxylaminato‐aminoxide Complex of Gallium | Zendy

Bösing Patrick | Zendy; Neumann Beate | Zendy; Stammler HansGeorg | Zendy; Mitzel Norbert W. | Zendy

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A Cyclic Hydroxylaminato‐aminoxide Complex of Gallium

Author(s) -

Bösing Patrick,

Neumann Beate,

Stammler HansGeorg,

Mitzel Norbert W.

Publication year - 2009

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200900340

Subject(s) - gallium , tautomer , chemistry , ligand (biochemistry) , ring (chemistry) , oxygen atom , crystal structure , crystallography , elemental analysis , stereochemistry , medicinal chemistry , inorganic chemistry , molecule , organic chemistry , receptor , biochemistry

The reaction of HON( t Bu)CH 2 CH 2 N( t Bu)OH with tri‐ tert ‐butyl gallium affords a hydroxylaminato complex of the formula [ t Bu 2 Ga{ON( t Bu)CH 2 CH 2 N(H)( t Bu)O}], which contains a monoanionic bishydroxylaminato ligand with one anionic and one neutral, but tautomeric aminoxide end, both linked to gallium by their oxygen atoms leading to a seven‐membered ring. The compound was characterised by elemental analysis, 1 H and 13 C NMR and determination of its crystal structure.

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