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Two‐Dimensional Lanthanide‐Containing Coordination Frameworks: Structure, Magnetic and Luminescence Properties
Author(s) -
Gao Ting,
Li GuangMing,
Yan PengFei,
Zhang JuWen,
Sun WenBin,
Suda Masayuki,
Einaga Yasuaki
Publication year - 2010
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200900300
Subject(s) - lanthanide , luminescence , antiferromagnetism , magnetism , ligand (biochemistry) , crystallography , materials science , metal , coordination complex , chemistry , condensed matter physics , organic chemistry , ion , metallurgy , physics , optoelectronics , biochemistry , receptor
Two lanthanide‐containing 2D coordination polymers, [ Ln (H 2 salen) 1.5 (NO 3 ) 3 ] n [H 2 salen = N , N′ ‐ ethylenebis(salicylideneimine); Ln = Gd ( 1 ), Dy ( 2 )], have been prepared by self‐assembly method. The molecular magnetism and luminescence of the metal complexes had been studied. Complex 1 exhibits antiferromagnetic interaction between spin carriers. Complex 2 emits the H 2 salen ligand luminescence.
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