Premium
[ t BuC(N i Pr) 2 ] 2 Zn as Starting Reagent for Monoamidinate Zinc Complexes {[ t BuC(N i Pr) 2 ]ZnX} 2
Author(s) -
Schmidt Sarah,
Schulz Stephan,
Bolte Michael
Publication year - 2009
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200900227
Subject(s) - zinc , reagent , chemistry , crystallography , nuclear magnetic resonance spectroscopy , spectroscopy , crystal structure , crystal (programming language) , stereochemistry , physics , organic chemistry , quantum mechanics , computer science , programming language
Reaction of the bisamidinate zinc complex [ t BuC(N i Pr) 2 ] 2 Zn ( 1 ) with ZnMe 2 yielded the corresponding monoamidinate zinc complex {[ t BuC(N i Pr) 2 ]ZnMe} 2 ( 2 ). Complex 2 reacts with iodine with formation of {[ t BuC(N i Pr) 2 ]ZnI} 2 ( 3 ). Compounds 2 and 3 both adopt dimeric structures in the solid state as was shown by single‐crystal X‐ray analyses. 2 and 3 were characterized by elemental analyses, mass and multinuclear ( 1 H, 13 C{ 1 H}) NMR spectroscopy ( 1 H, 13 C). In addition, X‐ray crystal structures of 1 – 3 are reported.