Three Lead(II) Complexes in One Coordination Polymer, [Pb(TpyCl)Cl][Pb(TpyCl)Cl 2 ][PbCl 3 ](CH 3 OH) | Zendy

Saghatforoush Lotfali | Zendy; Marandi Farzin | Zendy; Pantenburg Ingo | Zendy; Meyer Gerd | Zendy

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Three Lead(II) Complexes in One Coordination Polymer, [Pb(TpyCl)Cl][Pb(TpyCl)Cl 2 ][PbCl 3 ](CH 3 OH)

Author(s) -

Saghatforoush Lotfali,

Marandi Farzin,

Pantenburg Ingo,

Meyer Gerd

Publication year - 2009

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200900224

Subject(s) - cationic polymerization , chemistry , crystallography , coordination polymer , terpyridine , crystal structure , lone pair , ligand (biochemistry) , hydrogen bond , divalent , ion , polymer , coordination number , single crystal , inorganic chemistry , molecule , metal , polymer chemistry , biochemistry , receptor , organic chemistry

[Pb(TpyCl)Cl][Pb(TpyCl)Cl 2 ][PbCl 3 ](CH 3 OH) ( 1 ), a new coordination polymer of divalent lead with the ligand 4′‐chloro‐2,2′:6′,2"‐terpyridine (TpyCl), was obtained as single crystals by the branched tube method. The crystal structure contains three complexes, the cationic [Pb(TpyCl)Cl] + , the neutral [Pb(TpyCl)Cl 2 ] and the anionic [PbCl 3 ] – , which are connected through bridging chlorides and hydrogen bonds to a two‐dimensional coordination polymer. In all three complexes, the arrangement around the Pb 2+ ion suggests the existence of a stereoactive lone pair.

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