Synthesis and Structure of a Highly Chlorinated C 78 : C 78 (2)Cl 30 | Zendy

Troyanov Sergey I. | Zendy; Tamm Nadezhda B. | Zendy; Chen Chuanbao | Zendy; Yang Shangfeng | Zendy; Kemnitz Erhard | Zendy

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Synthesis and Structure of a Highly Chlorinated C 78 : C 78 (2)Cl 30

Author(s) -

Troyanov Sergey I.,

Tamm Nadezhda B.,

Chen Chuanbao,

Yang Shangfeng,

Kemnitz Erhard

Publication year - 2009

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200900206

Subject(s) - fullerene , ampoule , chemistry , molecule , crystal structure , carbon fibers , aromaticity , crystallography , medicinal chemistry , materials science , organic chemistry , composite number , composite material

A highly chlorinated C 78 fullerene, C 78 ( 2 )Cl 30 , was obtained by the reaction of the isomer C 78 ( 2 ) with SbCl 5 in ampoules at 330–340 °C. Single‐crystal structure determination revealed that the C 2 v ‐C 78 Cl 30 molecule contains only isolated double bonds and aromatic benzenoid rings in the C 78 carbon cage. Therefore, C 78 Cl 30 represents the highest possible chlorination degree for C 78 fullerenes obtained so far.

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