Premium
The Crystal Structures of the Cyanidofluoroborates K[BF x (CN) 4– x ], x = 0–4
Author(s) -
Bernhardt Eduard,
Willner Helge
Publication year - 2009
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200900153
Subject(s) - crystal structure , crystallography , unit (ring theory) , boron , chemistry , stereochemistry , physics , materials science , mathematics , mathematics education , organic chemistry
The crystal structure of K[BF 3 (CN)] ( Pbcn (Nr. 60) with a = 13.3486(15) b = 6.5239(7) c = 10.0085(11) Å, and eight formula units per unit cell) has been determined and the one of K[BF 2 (CN) 2 ] was confirmed and improved. The different networks in the complete series of borates K[BF x (CN) 4–x ], x = 0–4 are compared and discussed.