Bidentate Phosphine Oxides as Ligands to form Ga III  Shell Complexes. [Ga(CH 2 (P(O)Ph) 2 ) 3 ] 3+ : Synthesis, Structural and Spectroscopic Study | Zendy

Grachova E. V. | Zendy; Linti G. | Zendy; Protasova I. D. | Zendy; Tunik S. P. | Zendy

Premium

Bidentate Phosphine Oxides as Ligands to form Ga III Shell Complexes. [Ga(CH 2 (P(O)Ph) 2 ) 3 ] 3+ : Synthesis, Structural and Spectroscopic Study

Author(s) -

Grachova E. V.,

Linti G.,

Protasova I. D.,

Tunik S. P.

Publication year - 2009

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200900147

Subject(s) - homoleptic , denticity , octahedron , gallium , chemistry , phosphine oxide , cationic polymerization , crystallography , phosphine , nuclear magnetic resonance spectroscopy , oxide , oxidation state , inorganic chemistry , chelation , stereochemistry , metal , crystal structure , polymer chemistry , organic chemistry , catalysis

The tri‐cationic shell gallium complex [Ga(CH 2 (P(O)Ph) 2 ) 3 ] 3+ containing three neutral diphosphine oxide ligands has been synthesized and structurally characterized by using X‐ray crystallography, mass spectrometry, and 1 H, 13 C, 31 P, and 71 Ga NMR spectroscopy. The ligands form three equivalent six‐membered chelate cycles to give an idealized octahedral environment around the Ga 3+ ion. This compound is the first example of a mononuclear homoleptic octahedral structure formed by neutral phosphine oxide ligands in the chemistry of the 13 group elements in the +3 oxidation state.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research