The First Ruthenium Complex of a Heteroleptic Organostannylene: [4‐ t Bu‐2,6‐{P(O)(O‐ i Pr) 2 } 2 C 6 H 2 ]Sn(Cl)Ru(C 6 H 6 )Cl 2 | Zendy

Deaáky Vajk | Zendy; Schürmann Markus | Zendy; Jurkschat Klaus | Zendy

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The First Ruthenium Complex of a Heteroleptic Organostannylene: [4‐ t Bu‐2,6‐{P(O)(O‐ i Pr) 2 } 2 C 6 H 2 ]Sn(Cl)Ru(C 6 H 6 )Cl 2

Author(s) -

Deaáky Vajk,

Schürmann Markus,

Jurkschat Klaus

Publication year - 2009

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200900045

Subject(s) - ruthenium , chemistry , intramolecular force , crystallography , tin , toluene , trigonal bipyramidal molecular geometry , crystal structure , x ray crystallography , nuclear magnetic resonance spectroscopy , stereochemistry , pentagonal bipyramidal molecular geometry , atom (system on chip) , spectroscopy , diffraction , catalysis , physics , organic chemistry , quantum mechanics , computer science , optics , embedded system , biochemistry

The synthesis of the intramolecularly coordinated organostannylene ruthenium complex [4‐ t Bu‐2,6‐{P(O)(O‐ i Pr) 2 } 2 ‐C 6 H 2 ]Sn(Cl)Ru(C 6 H 6 )Cl 2 , 1 , is reported. It is characterized by elemental analysis, 1 H, 13 C, 31 P, 119 Sn NMR spectroscopy, and, as its toluene solvate 1 ·C 7 H 8 , by single‐crystal X‐ray diffraction analysis. In compound 1 ·C 7 H 8 the tin atom is five‐coordinate and shows a strongly distorted trigonal‐bipyramidal configuration. The intramolecular O–Sn distances are 2.291(3) and 2.394(3) Å. The Sn–Ru distance is 2.5856 Å.

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