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Preparation and Molecular Structure of a Cyclic Bisgermylene with two Lutidine Bridging Groups
Author(s) -
Hahn F. Ekkehardt,
Zabula Alexander V.,
Pape Tania,
Hupka Florian
Publication year - 2009
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200801421
Subject(s) - bridging (networking) , intramolecular force , solid state , molecule , chemistry , crystallography , stereochemistry , organic chemistry , computer network , computer science
The cyclic tetraamine 2 , prepared by the hydrogenation of tetraimine 1 , was used for the preparation of the macrocyclic bisgermylene 3 with two lutidine bridging groups. The molecular structure determination of tetraamine 2 exhibits a C i ‐symmetric molecule in the solid state. The macrocyclic bisgermylene 3 shows weak intramolecular Ge···Ge and Ge···N interactions in the solid state.