A Hydrogen‐Bonded Framework Complex without Lattice Solvents: Synthesis Reversible Crystal‐to‐Amorphous Transformation and Chromic Properties | Zendy

Xiao Weiming | Zendy; Zhang Ning | Zendy; Deng Shengjun | Zendy; Mao Xuejin | Zendy; Chen Chao | Zendy

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A Hydrogen‐Bonded Framework Complex without Lattice Solvents: Synthesis Reversible Crystal‐to‐Amorphous Transformation and Chromic Properties

Author(s) -

Xiao Weiming,

Zhang Ning,

Deng Shengjun,

Mao Xuejin,

Chen Chao

Publication year - 2009

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200801403

Subject(s) - amorphous solid , materials science , crystal structure , lattice (music) , methanol , crystallography , chromic acid , hydrogen , crystal (programming language) , biphenyl , photochemistry , chemistry , organic chemistry , physics , computer science , acoustics , programming language

Reaction of Ni(NO 3 ) 2 ·6H 2 O with H 4 BPTC (H 4 BPTC = Biphenyl‐3,3′,4,4′‐tetracarboxylic acid) produced a 3D hydrogen‐bonded framework complex 1 , not containing lattice solvents, with empirical formula [Ni(H 2 O) 6 ]·H 2 BPTC. The complex exhibits an interesting reversible crystal‐to‐amorphous transformation property unaccompanied by lattice solvents release/loading and shows selective and reversible chromic response to methanol.

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