A Novel  μ  2 ‐(H 2 O)‐Bridged Double‐Chain Coordination Polymer [Cd(pc)(phen)(H 2 O)]  n   with Rhombic Grids (H 2 pc = pamoic acid, phen = 1,10‐phenanthroline) | Zendy

Han GuangXi | Zendy; Song YongJuan | Zendy; Zhao PengCheng | Zendy; Chen Xia | Zendy; Han ZhengBo | Zendy

Premium

A Novel μ 2 ‐(H 2 O)‐Bridged Double‐Chain Coordination Polymer [Cd(pc)(phen)(H 2 O)] n with Rhombic Grids (H 2 pc = pamoic acid, phen = 1,10‐phenanthroline)

Author(s) -

Han GuangXi,

Song YongJuan,

Zhao PengCheng,

Chen Xia,

Han ZhengBo

Publication year - 2009

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200801384

Subject(s) - crystallography , triclinic crystal system , stacking , zigzag , coordination polymer , hydrogen bond , intermolecular force , chemistry , molecule , hexacoordinate , hydrothermal synthesis , crystal structure , chain (unit) , hydrothermal circulation , stereochemistry , materials science , physics , geometry , mathematics , organic chemistry , astronomy , seismology , silicon , geology

A novel coordination polymer [Cd(pc)(phen)(H 2 O)] n (H 2 pc = pamoic acid, phen = 1,10‐phenanthroline) has been synthesized under hydrothermal conditions. Single crystal X‐ray diffraction analysis reveals that the compound crystallizes in triclinic space group P 1. All the Cd II atoms in the compound are hexacoordinate and are linked by pamoicate ligands to form a one‐dimensional zigzag chain. Furthermore, two adjacent zigzag chains are connected by the μ 2 ‐(H 2 O) molecules to form a double‐chain with rhombic grids. There exist intermolecular C–H ··· π contacts, π–π stacking and hydrogen‐bonding interactions. Compound 1 displays strong fluorescent emission in the solid state at room temperature.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research