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Synthesis and Characterization of β ‐Diketiminate Zinc Complexes
Author(s) -
Schulz Stephan,
Eisenmann Tamara,
Bläser Dieter,
Boese Roland
Publication year - 2009
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200801382
Subject(s) - zinc , potassium , chemistry , monomer , nuclear magnetic resonance spectroscopy , sodium , salt (chemistry) , elemental analysis , nuclear chemistry , medicinal chemistry , spectroscopy , inorganic chemistry , mass spectrometry , characterization (materials science) , crystal structure , crystallography , stereochemistry , organic chemistry , materials science , chromatography , polymer , nanotechnology , physics , quantum mechanics
Reactions of the monomeric β ‐diketiminate zinc complex MesNacNacZnMe (MesNacNac = {[2,6‐(2,4,6‐Me 3 –C 6 H 2 )‐N(Me)C)] 2 CH}) with ROH (R = Me, Et, i Pr) yielded the corresponding zinc alkoxides [MesNacNacZnOR] 2 (R = Me 1 , Et 2 , i Pr 3 ). In addition, the reaction of MesNacNacZnCl with various reducing agents such as potassium graphite, potassium, or sodium gave the Zn II complex [MesNacNac] 2 Zn 4 . Compounds 1 – 4 were characterized by elemental analyses, mass and multinuclear ( 1 H, 13 C{ 1 H}) NMR spectroscopy, and by single‐crystal X‐ray analysis.
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