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Trilithium Trisaminotriazinates
Author(s) -
Glatz Germund,
Motz Günter,
Kempe Rhett
Publication year - 2009
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200801373
Subject(s) - dimethoxyethane , deprotonation , tris , chemistry , lithium (medication) , solid state , medicinal chemistry , crystallography , stereochemistry , organic chemistry , ion , electrolyte , medicine , biochemistry , electrode , endocrinology
Two trilithium‐tris(trimethylsilylamino)triazinates were prepared from the reaction of three equivalents n BuLi and one equivalent 2,4,6‐tris(trimethylsilyamino)‐1,3,5‐triazine (Tr TMS3 H 3 ) in tetrahydrofurane (THF) or dimethoxyethane (DME). Concentration of the mother liquor gave single crystals suitablefor X‐ray diffraction. The solid‐state structures of [(Tr TMS3 ) 2 Li 6 (THF) 8 ]·2THF ( 1 ) and [(Tr TMS3 ) 2 Li 6 (DME) 4 ] ( 2 ) were determined. Two triply deprotonated Tr TMS3 ligands are bridged by four lithium atoms.
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