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Solvothermal Synthesis, Crystal Structure and Properties of the First Organic‐templated Holmium Sulfate [C 2 N 2 H 10 ] 3 [Ho 2 (SO 4 ) 6 ·2H 2 O]
Author(s) -
Zhou Wanli,
Chen Qi,
Zhu Dunru,
Xu Yan
Publication year - 2009
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200801330
Subject(s) - zigzag , crystallography , solvothermal synthesis , thermogravimetric analysis , holmium , crystal structure , crystal (programming language) , materials science , sulfate , single crystal , diffraction , hydrothermal synthesis , hydrothermal circulation , chemistry , organic chemistry , chemical engineering , physics , laser , programming language , geometry , mathematics , computer science , optics , metallurgy , engineering
Abstract The first organic amine‐templated holmium sulfate [C 2 N 2 H 10 ] 3 [Ho 2 (SO 4 ) 6 ·2H 2 O] ( 1 ) has been synthesized solvothermally and has been structurally characterized by single‐crystal X‐ray diffraction studies, IR spectroscopic, thermogravimetric (TG) and inductivity coupled plasma (ICP) measurements. Crystal analyses of compound 1 showed a novel inorganic layer constructed from the zigzag and helical [–Ho–O–S–O–] n chains, both of the chains are connected by μ‐2 SO 4 2– groups to form 10‐membered rings. The solvent plays an important role during the formation of 1 .