Premium
Synthesis, Structure and Photoluminescent Properties of [C 6 N 2 H 14 ][Nd 2 (C 2 O 4 ) 2 (SO 4 ) 2 (H 2 O) 4 ]·H 2 O, a New Organically Templated Neodymium(III) Oxalate‐sulfate
Author(s) -
Xu Ning,
Xing Yan,
Liu Xianchun,
Song Danhui,
Ma Ling,
Sun Xiujuan
Publication year - 2009
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200801309
Subject(s) - neodymium , luminescence , oxalate , photoluminescence , sulfate , crystal structure , crystallography , hydrothermal circulation , ion , hydrothermal synthesis , materials science , chemistry , x ray crystallography , diffraction , inorganic chemistry , physics , optics , laser , geology , optoelectronics , organic chemistry , seismology , metallurgy
An organically templated neodymium oxalate–sulfate [C 6 N 2 H 14 ][Nd 2 (C 2 O 4 ) 2 (SO 4 ) 2 (H 2 O) 4 ]·H 2 O ( 1 ) has been synthesized under hydrothermal conditions and structurally characterized by single‐crystal X‐ray diffraction analysis. In 1 , the neodymium(III) ions are interconnected through oxalate and sulfate groups to form a neodymium oxalate–sulfate hybrid structure. A luminescence spectrum of 1 was recorded, and the luminescence decay time was also measured.