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Synthesis of Chloro Boryl Complexes by Oxidative Addition of B–Cl Bonds
Author(s) -
Braunschweig Holger,
Fuß Marco,
Radacki Krzysztof,
Uttinger Katharina
Publication year - 2009
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200800426
Subject(s) - oxidative addition , chemistry , oxidative phosphorylation , platinum , ligand (biochemistry) , nuclear magnetic resonance spectroscopy , medicinal chemistry , stereochemistry , organic chemistry , catalysis , receptor , biochemistry
Some platinum boryl complexes of the type trans ‐[(Cy 3 P) 2 Pt(Cl){B(Cl)R}] ( 1 : R = NMe 2 , 2 : R = Mes, 3 : R = t Bu) were synthesized by oxidative addition of the corresponding dichloroboranes to [Pt(PCy 3 ) 2 ]. All the compounds were characterized by multinuclear NMR spectroscopy in solution. Furthermore, a single crystal analysis was acquired from 2 , that confirms the strong trans ‐influence of this boryl ligand.