Premium
Solvent‐Induced Pseudopolymorphism of a New Dinuclear Oxovanadium(V) Compound Based on 2,6‐Di(hydroxymethyl)‐4‐methylphenol
Author(s) -
Chen Lian,
Jiang Feilong,
Wu Mingyan,
Li Ning,
Xu Wentao,
Yan Chunfeng,
Hong Maochun
Publication year - 2009
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200800393
Subject(s) - acetylacetone , hydroxymethyl , chemistry , hydrogen bond , solvent , single crystal , crystallography , stereochemistry , crystal structure , infrared spectroscopy , x ray crystallography , diffraction , medicinal chemistry , molecule , organic chemistry , physics , optics
Reactions of VO 2 (acac) (Hacac = acetylacetone) and 2,6‐Di(hydroxymethyl)‐4‐methylphenol (H 3 L) in different organic solvents give rise to two pseudopolymorphs of a new dinuclear oxovanadium(V) compound, [Et 3 NH] 2 [V 2 O 4 (HL) 2 ] ( 1 ) and [Et 3 NH] 2 [V 2 O 4 (HL) 2 ]·H 2 O ( 2 ). The compounds have been synthesized and characterized by elemental analyses, IR spectra and single‐crystal X‐ray diffraction. X‐ray diffraction analyses reveal that 1 and 2 have different weak interactions and display remarkably distinct hydrogen‐bonded networks.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom