Synthesis and Structure of a Hybrid Metal Phthalate Compound and Its Magnetic Property | Zendy

Wu Wen | Zendy; Xie JiMin | Zendy; Xuan YaWen | Zendy

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Synthesis and Structure of a Hybrid Metal Phthalate Compound and Its Magnetic Property

Author(s) -

Wu Wen,

Xie JiMin,

Xuan YaWen

Publication year - 2009

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200800355

Subject(s) - phthalate , monoclinic crystal system , chemistry , nickel , crystallography , crystal structure , hydrogen bond , metal , crystallization , alkali metal , inorganic chemistry , stereochemistry , molecule , organic chemistry

The hybrid transition metal – alkali metal compound, [Ni(H 2 O) 6 ·( μ ‐H 2 O) 2 ·K 2 (phth) 4 (H 2 O)], (phth = phthalate) ( 1 ), was synthesized from nickel(II) nitrate, KOH and potassium hydrogen phthalate, and was isolated by crystallization. Single‐crystal X‐ray analysis revealed that 1 belongs to the monoclinic system, space group P 2 1 / c with a = 10.455(2) Å, b = 6.8670(14) Å, c = 29.704(6) Å, γ = 98.14(3)°, R 1 = 0.0585, wR 2 = 0.1503. In the title compound, [K 2 (phth) 4 ] 2+ units are bonded to water‐bridged Ni chains forming 2D lamellar‐like compounds.

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