A Gadolinium Complex of the 5‐(1 H ‐Tetrazol‐5‐yl)isophthalic Acid Ligand: [Gd(C 9 H 3 N 4 O 4 )(H 2 O) 3 ·2H 2 O] n | Zendy

Qu ZhiRong | Zendy; Xing Zheng | Zendy; Wu BaoZhen | Zendy; Li XiuZhi | Zendy; Han GuangFan | Zendy

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A Gadolinium Complex of the 5‐(1 H ‐Tetrazol‐5‐yl)isophthalic Acid Ligand: [Gd(C 9 H 3 N 4 O 4 )(H 2 O) 3 ·2H 2 O] n

Author(s) -

Qu ZhiRong,

Xing Zheng,

Wu BaoZhen,

Li XiuZhi,

Han GuangFan

Publication year - 2009

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200800347

Subject(s) - triclinic crystal system , isophthalic acid , crystallography , gadolinium , ligand (biochemistry) , crystal structure , chemistry , solid state , fluorescence , stereochemistry , physics , receptor , biochemistry , organic chemistry , quantum mechanics , polyester , terephthalic acid

The reaction of Gd(ClO 4 ) 3 ·6H 2 O with 5‐(1 H ‐tetrazol‐5‐yl)isophthalic acid affords a 3D framework gadolinium coordination polymer, [Gd(C 9 H 3 N 4 O 4 )(H 2 O) 3 ·2H 2 O] n ( 1 ). Its crystal structure belongs to a triclinic system, space group $P{\bar 1}$ , with a = 7.909(2) Å; b = 8.448(2) Å; c = 10.994(2) Å; α = 102.65(3)°; β = 124.32(2)°; γ = 96.28(3)°; V = 704.5(2) Å 3 ; Z = 2; R 1 = 0.0245 for 3225 reflections with I >2σ( I ), wR 2 = 0.0556. Fluorescent analyses show that compound 1 exhibits purple fluorescence in the solid state at room temperature.

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