Synthesis, IR Spectrum, Thermal Analysis, and Crystal Structure of the Cyano‐bridged Heteronuclear Polymeric Complex: [Zn(teta)Ni(μ‐CN) 2 (CN) 2 ] n | Zendy

Kürkçüoğlu Güneş Süheyla | Zendy; Yeşilel Okan Zafer | Zendy; Kavlak Ilkan | Zendy; Büyükgüngör Orhan | Zendy

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Synthesis, IR Spectrum, Thermal Analysis, and Crystal Structure of the Cyano‐bridged Heteronuclear Polymeric Complex: [Zn(teta)Ni(μ‐CN) 2 (CN) 2 ] n

Author(s) -

Kürkçüoğlu Güneş Süheyla,

Yeşilel Okan Zafer,

Kavlak Ilkan,

Büyükgüngör Orhan

Publication year - 2009

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200800337

Subject(s) - heteronuclear molecule , monoclinic crystal system , triethylenetetramine , crystallography , crystal structure , octahedron , thermal decomposition , infrared spectroscopy , chemistry , thermal analysis , ion , single crystal , x ray crystallography , inorganic chemistry , stereochemistry , diffraction , nuclear magnetic resonance spectroscopy , thermal , physics , organic chemistry , meteorology , optics

The heteronuclear polymeric complex, [Zn(teta)Ni(μ‐CN) 2 (CN) 2 ] n (teta: triethylenetetramine), was synthesized and characterized by elementel analysis, FT‐IR spectroscopy, thermal analysis and single crystal X–ray diffraction techniques. The complex crystallizes in the monoclinic system, space group P 2 1 / c and in which the Zn II ion exhibits a distorted octahedral coordination by one tetradentate teta ligand and two bridging cyano groups as a trans position, whereas the Ni II ion has square planer coordination and is coordinated by four cyano ligands. The decomposition reaction takes places in the temperature range 30–600 °C in the static air atmosphere.

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