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Trifluoromethylphenyl Palladium(II) Complexes – Synthesis and Characterization
Author(s) -
Czauderna Christine,
Wurziger Hanns,
Sun Yu,
Thiel Werner R.
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200800336
Subject(s) - palladium , phosphine , chemistry , benzene , derivatization , oxidative addition , medicinal chemistry , solid state , stereochemistry , organic chemistry , catalysis , high performance liquid chromatography
4‐Bromotrifluoromethyl benzene efficiently undergoes oxidative addition to palladium(0) precursors to give phosphine stabilized bromo(4‐trifluoromethylphenyl)palladium(II) complexes in high yields. Exchange of the bromo and the phosphine ligands allows further derivatization of these compounds. The solid state structures of two palladium(II) complexes of the type (L‐L)Pd(Br)(C 6 H 4 CF 3 ), with L‐L either performing cis or trans coordination could be elucidated.