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The Crystal Structures of Trimethylphosphane supported Nickel‐ and Cobalt‐Methyl Complexes: Octahedral mer‐cis‐ [Co III I(CH 3 ) 2 (PMe 3 ) 3 ] and Square Planar trans ‐[Ni II Cl(CH 3 )(PMe 3 ) 2 ]
Author(s) -
Beck Robert,
Klein HansFriedrich
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200800254
Subject(s) - octahedron , nickel , crystallography , cobalt , chemistry , crystal structure , pentane , x ray crystallography , stereochemistry , inorganic chemistry , physics , diffraction , organic chemistry , optics
Single crystals of octahedral mer‐cis‐ [Co III I(CH 3 ) 2 (PMe 3 ) 3 ] ( 1 ) and square planar trans ‐[Ni II Cl(CH 3 )(PMe 3 ) 2 ] ( 2 ), were obtained from solvent mixtures (methylcylohexane / pentane 1:1) and have been analyzed by X‐ray crystallography for the first time.