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Synthesis and Characterization of the First Salts of the ortho ‐Selenidoindate Anion [InSe 4 ] 5−
Author(s) -
Heine Johanna,
Dehnen Stefanie
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200800233
Subject(s) - ion , hydrate , chemistry , potassium , crystallography , inorganic chemistry , characterization (materials science) , crystal structure , materials science , organic chemistry , nanotechnology
Single‐crystalline potassium salts of the so far unknown ortho ‐selenidoindate anion [InSe 4 ] 5− , K 12 [InSe 4 ] 2 Se ( 1 ), K 9 [InSe 4 ][Se 2 ]Se ( 2 ), and a novel hydrate of the decaselenidotetraindate anion [In 4 Se 10 ] 8− , [K 8 (H 2 O) 11 ][In 4 Se 10 ] ( 3 ), were prepared and structurally characterized by means of X‐ray diffractometry. The investigations complete the series of known ortho‐ chalcogenidoindate anions and show further peculiarities of the indate chemistry with respect to the properties of related stannates.