Kristallstruktur des Lithium‐Trimethylsilanolats [Li 7 (OSiMe 3 ) 7 (THF)] | Zendy

Kern Beatrice | Zendy; Vitze Hannes | Zendy; Bolte Michael | Zendy; Wagner Matthias | Zendy; Lerner HansWolfram | Zendy

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Kristallstruktur des Lithium‐Trimethylsilanolats [Li 7 (OSiMe 3 ) 7 (THF)]

Author(s) -

Kern Beatrice,

Vitze Hannes,

Bolte Michael,

Wagner Matthias,

Lerner HansWolfram

Publication year - 2008

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200800185

Subject(s) - tetrahydrofuran , lithium (medication) , toluene , chemistry , trigonal crystal system , ligand (biochemistry) , crystal structure , crystallography , organic chemistry , medicine , biochemistry , receptor , solvent , endocrinology

The lithium silanolate LiOSiMe 3 is accessible from the reaction of Me 3 SiOSiMe 3 with LiMe in tetrahydrofuran. Single crystals of [Li 7 (OSiMe 3 ) 7 (THF)] were obtained from toluene at 25 °C. The structure of [Li 7 (OSiMe 3 ) 7 (THF)] ( C 2/ c ) features a capped trigonal antiprismatic arrangement of seven Li atoms. The Li atoms in [Li 7 (OSiMe 3 ) 7 (THF)] are μ 3 ‐bridged by seven O atoms of the silanolate ligand.

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