Premium (Cyclopentadienyl)trioxorhenium(VII) – no Match for Methyltrioxorhenium (MTO)
Högerl Manuel,
Kühn Fritz E.
Publication year2008
Publication title
zeitschrift für anorganische und allgemeine chemie
Resource typeJournals
Abstract Together with a further improvement of the synthesis of (cyclopentadienyl)trioxorhenium(VII), CpReO 3 , its reaction chemistry and catalytic activity is also revisited in greater detail. However, in spite of the high catalytic activity of the homologous methyltrioxorhenium(VII) (MTO) and the related CpMo(O 2 )X, (X = R, Hal, etc.) it is seen that CpReO 3 suffers greatly from the lability of the Cp‐Re bond under oxidative conditions and in the presence of electron donor ligands. (Cyclopentadienyl)trioxorhenium(VII) although accessible very conveniently, neither matches the rich reaction chemistry of its pentamethylcyclopentadienyl derivative, Cp*ReO 3 nor the catalytic versatility of MTO.
Subject(s)catalysis , chemistry , combinatorial chemistry , cyclopentadienyl complex , derivative (finance) , economics , financial economics , lability , medicinal chemistry , organic chemistry
SCImago Journal Rank0.354

Seeing content that should not be on Zendy? Contact us.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here