Synthesis and Characterization of Gallium(III) and Germanium(II) Chlorides Bearing the C 6 F 5 ‐Substituted  β ‐Diketiminate HC[(CMe)(NC 6 F 5 )] 2  Ligand | Zendy

Yang Zhi | Zendy; Ma Xiaoli | Zendy; Roesky Herbert W. | Zendy; Yang Ying | Zendy; Zhu Hongping | Zendy; Magull Jörg | Zendy; Ringe Arne | Zendy

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Synthesis and Characterization of Gallium(III) and Germanium(II) Chlorides Bearing the C 6 F 5 ‐Substituted β ‐Diketiminate HC[(CMe)(NC 6 F 5 )] 2 Ligand

Author(s) -

Yang Zhi,

Ma Xiaoli,

Roesky Herbert W.,

Yang Ying,

Zhu Hongping,

Magull Jörg,

Ringe Arne

Publication year - 2008

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200800087

Subject(s) - germanium , gallium , lithium (medication) , salt (chemistry) , germanium compounds , ligand (biochemistry) , chemistry , crystal structure , characterization (materials science) , inorganic chemistry , single crystal , crystallography , materials science , nanotechnology , organic chemistry , receptor , silicon , endocrinology , medicine , biochemistry

The germanium(II) and gallium(III) organochlorides containing the C 6 F 5 ‐substituted β ‐diketiminate ligand LGeCl ( 2 ) and LGaCl 2 ( 3 ) (L = HC[(CMe)(NC 6 F 5 )] 2 ) were synthesized. Salt elimination reactions of the C 6 F 5 ‐substituted β ‐diketiminato lithium salt with the corresponding germanium(II) and gallium(III) chlorides led to the organochlorides respectively. Compounds 2 and 3 were characterized by spectroscopic and elemental analyses, and 2 was further investigated by single crystal X‐ray structural analysis.

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