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Synthesis and Characterization of Gallium(III) and Germanium(II) Chlorides Bearing the C 6 F 5 ‐Substituted β ‐Diketiminate HC[(CMe)(NC 6 F 5 )] 2 Ligand
Author(s) -
Yang Zhi,
Ma Xiaoli,
Roesky Herbert W.,
Yang Ying,
Zhu Hongping,
Magull Jörg,
Ringe Arne
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200800087
Subject(s) - germanium , gallium , lithium (medication) , salt (chemistry) , germanium compounds , ligand (biochemistry) , chemistry , crystal structure , characterization (materials science) , inorganic chemistry , single crystal , crystallography , materials science , nanotechnology , organic chemistry , receptor , silicon , endocrinology , medicine , biochemistry
The germanium(II) and gallium(III) organochlorides containing the C 6 F 5 ‐substituted β ‐diketiminate ligand LGeCl ( 2 ) and LGaCl 2 ( 3 ) (L = HC[(CMe)(NC 6 F 5 )] 2 ) were synthesized. Salt elimination reactions of the C 6 F 5 ‐substituted β ‐diketiminato lithium salt with the corresponding germanium(II) and gallium(III) chlorides led to the organochlorides respectively. Compounds 2 and 3 were characterized by spectroscopic and elemental analyses, and 2 was further investigated by single crystal X‐ray structural analysis.