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The Bis‐{Co 2 (μ‐dppm)(CO) 4 } Adduct of Dimethyl hex‐3‐en‐1,5‐diyne‐1,6‐dicarboxylate
Author(s) -
Bruce Michael I.,
Skelton Brian W.,
White Allan H.,
Zaitseva Natasha N.
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200800021
Subject(s) - adduct , chemistry , derivative (finance) , medicinal chemistry , context (archaeology) , substitution (logic) , stereochemistry , hydrogen , organic chemistry , paleontology , computer science , financial economics , economics , biology , programming language
The synthesis and structural characterization of a bis‐dicobalt derivative of dimethyl hex‐3‐en‐1,5‐diyne‐1,6‐dicarboxylate, [{Co 2 (μ‐dppm)(CO) 4 } 2 (μ:μ‐MeO 2 CC 2 CH=CHC 2 CO 2 Me)]·2CHCl 3 ( 1 ) is described, permitting, in the context of previous related studies, comparison of the effects of progressive substitution of the ethene hydrogen atoms by C≡C·SiMe 3 groupings.