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A New Anderson‐type Heteropolyanion‐Supported Transition Metal Complex: [Himi] 2 [Ni(imi) 3 (H 2 O){Ni(OH) 6 Mo 6 O 18 }]·2H 2 O
Author(s) -
Li Jing,
Zhang LanCui,
Sun ZhenGang,
Tian CuiHua,
Zhu ZaiMing,
Zhao Yan,
Zhu YanYu,
Zhang Jing,
Zhang Na,
Liu Lei,
Lu Xin
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700599
Subject(s) - crystallography , infrared spectroscopy , imidazole , transition metal , nickel , aqueous solution , thermogravimetric analysis , supramolecular chemistry , hydrogen bond , crystal structure , spectroscopy , materials science , elemental analysis , chemistry , single crystal , covalent bond , inorganic chemistry , molecule , stereochemistry , physics , catalysis , organic chemistry , quantum mechanics
A new Anderson‐type heteropolyanion‐supported nickel imidazole complex, [Himi] 2 [Ni(imi) 3 (H 2 O){Ni(OH) 6 Mo 6 O 18 }]·2H 2 O (imi = imidazole) ( 1 ) has been prepared by conventional aqueous solution synthesis and structurally characterized by single‐crystal X‐ray diffraction as well as by infrared spectroscopy, elemental and thermogravimetric analysis. Compound 1 possesses a one‐dimensional (1D) wave‐like infinite chain structure composed of Anderson‐type heteropolyanion [Ni(OH) 6 Mo 6 O 18 ] 4− covalently linked by [Ni(imi) 3 (H 2 O)] 2+ unit. Furthermore, the chains are extended into a 2D supramolecular framework in the ac plane via hydrogen‐bonding interactions.