Premium
Supramolecular Structure Formed by Directed Intermolecular Interactions in a Lead(II) Complex
Author(s) -
Marandi Farzin,
Fun HoongKun
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700587
Subject(s) - supramolecular chemistry , stacking , intermolecular force , crystallography , chemistry , acceptor , crystal structure , non covalent interactions , ligand (biochemistry) , stereochemistry , hydrogen bond , single crystal , nuclear magnetic resonance spectroscopy , molecule , organic chemistry , biochemistry , condensed matter physics , physics , receptor
To investigate the interactions between noncovalent bond donor and acceptor giving rise to three dimensional networks, compound [Pb(tfpb) 2 ] n (Htfpb = 4,4,4‐trifluoro‐1‐phenyl‐1,3‐butanedione) has been prepared and characterized by elemental analysis, IR, 1 H NMR, and 13 C NMR spectroscopy and its crystal structure was investigated. The single‐crystal structure of the compound show the coordination number of Pb(II) to be eight with six O‐donor atoms from a “tfpb” ligand and two F‐donors from the anionic ligands. The supramolecular structure of 1 is realized by weak directional C–F···F–C and π–π stacking interactions.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom