Premium
Gas Storages in Microporous Metal‐Organic Framework at Ambient Temperature
Author(s) -
Zhu LongGuan,
Xiao HongPing
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700580
Subject(s) - microporous material , methane , adsorption , metal organic framework , elemental analysis , chemistry , single crystal , inorganic chemistry , metal , hydrogen , nuclear chemistry , materials science , organic chemistry , crystallography
[Co 2 (bdc) 2 (ted)]·2DMF·3H 2 O ( 2 ), (DMF = N,N′‐dimethylformamide, bdc = 1,4‐benzenedicarboxylate dianion, ted = triethylenediamine) was prepared and characterized by IR, elemental analysis, TGA, powder X‐ray analysis and single‐crystal X‐ray determination. At ambient temperature the material [Co 2 (bdc) 2 (ted)] ( 1 ) was found to be high adsorbent of methane but poor adsorbent of hydrogen.