Premium
[PdCl(TeMe 2 ) 3 ](BAr F ) – The First Structurally Characterized Palladium(II) Complex with TeMe 2 Ligands
Author(s) -
Bröring Martin,
Kleeberg Christian
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700575
Subject(s) - palladium , cationic polymerization , toluene , chemistry , pentane , crystallography , medicinal chemistry , crystallization , stereochemistry , bar (unit) , ion , polymer chemistry , catalysis , organic chemistry , physics , meteorology
[PdCl(TeMe 2 ) 3 ]BAr F ( 4 ) forms as the major tellurium containing product from the reaction of [(4‐Mebti)PdCl] with TeMe 2 and Na(BAr F ) and is isolated by crystallization from the reaction mixture. At −20 °C, the compound forms orange columns from toluene/pentane, space group $P{\bar 1}$ , with Z = 2. In the solid, the cationic [PdCl(TeMe 2 ) 3 ] + complex ions show a non‐planar PdClTe 3 coordination unit and are associated to dimers via weak Pd···Te interactions.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom