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[PdCl(TeMe 2 ) 3 ](BAr F ) – The First Structurally Characterized Palladium(II) Complex with TeMe 2 Ligands
Author(s) -
Bröring Martin,
Kleeberg Christian
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700575
Subject(s) - palladium , cationic polymerization , toluene , chemistry , pentane , crystallography , medicinal chemistry , crystallization , stereochemistry , bar (unit) , ion , polymer chemistry , catalysis , organic chemistry , physics , meteorology
[PdCl(TeMe 2 ) 3 ]BAr F ( 4 ) forms as the major tellurium containing product from the reaction of [(4‐Mebti)PdCl] with TeMe 2 and Na(BAr F ) and is isolated by crystallization from the reaction mixture. At −20 °C, the compound forms orange columns from toluene/pentane, space group $P{\bar 1}$ , with Z = 2. In the solid, the cationic [PdCl(TeMe 2 ) 3 ] + complex ions show a non‐planar PdClTe 3 coordination unit and are associated to dimers via weak Pd···Te interactions.