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Synthesis and Characterization of MoFe 3 S 4 and Mo 2 Fe 2 S 4 Single Cubanes
Author(s) -
Koutmos Markos,
Georgakaki Irene P.,
Tsiolis Panagiotis,
Coucouvanis Dimitri
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700419
Subject(s) - characterization (materials science) , chemistry , coupling (piping) , combinatorial chemistry , nanotechnology , materials science , metallurgy
The synthesis of multimetallic M/S clusters by the reductive coupling of dimeric building blocks appears to be of general utility. In this paper we describe the synthesis and characterization of new single cubanes with cores such as [Mo 2 Fe 2 S 4 ] 2+ and [MoFe 3 S 4 ] 3+,2+ .