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The Crystal Structure of Dimethylamino Titanium Trichloride
Author(s) -
Günther Bernd,
Nöth Heinrich
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700418
Subject(s) - titanium , group (periodic table) , crystallography , atom (system on chip) , crystal structure , crystal (programming language) , chain (unit) , materials science , planar , chemistry , metallurgy , organic chemistry , physics , computer graphics (images) , astronomy , computer science , programming language , embedded system
Green crystals of Me 2 NTiCl 3 associate to a chain polymer via four Ti‐Cl‐Ti bonds and generation of hexacoordinated Ti atoms. Like Et 2 NTiCl 3 its amino group is not involved into forming Ti‐N‐Ti bridges. This is due to a short Ti‐N bond to the planar coordinated N atom of the Me 2 N group.