The Crystal Structure of Dimethylamino Titanium Trichloride | Zendy

Günther Bernd | Zendy; Nöth Heinrich | Zendy

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The Crystal Structure of Dimethylamino Titanium Trichloride

Author(s) -

Günther Bernd,

Nöth Heinrich

Publication year - 2008

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200700418

Subject(s) - titanium , group (periodic table) , crystallography , atom (system on chip) , crystal structure , crystal (programming language) , chain (unit) , materials science , planar , chemistry , metallurgy , organic chemistry , physics , computer graphics (images) , astronomy , computer science , programming language , embedded system

Green crystals of Me 2 NTiCl 3 associate to a chain polymer via four Ti‐Cl‐Ti bonds and generation of hexacoordinated Ti atoms. Like Et 2 NTiCl 3 its amino group is not involved into forming Ti‐N‐Ti bridges. This is due to a short Ti‐N bond to the planar coordinated N atom of the Me 2 N group.

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