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Hydrogen Bonds in Rubidium Amide‐Ammonia(3/2), RbNH 2 ·2/3NH 3
Author(s) -
Scheubeck Thomas,
Korber Nikolaus
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700381
Subject(s) - rubidium , hydrogen bond , liquid ammonia , ammonia , amide , molecule , crystallography , crystal structure , hydrogen , chemistry , crystal (programming language) , inorganic chemistry , materials science , potassium , organic chemistry , computer science , programming language
Rubidium amide‐ammonia(3/2), RbNH 2 ·2/3NH 3 , was synthesized from Rubidiumhydride, RbH, in liquid ammonia at −78 °C. The compound crystallizes in the cubic space group I 2 1 3 with Z = 4, a = 10.0490(12) Å, and V = 1014.77(20) Å as isometric colorless crystals. The crystal structure was solved from single‐crystal X‐ray data. The structure contains a three‐dimensional network of amide anions and ammonia molecules, which are interconnected via hydrogen bonds.